194 lines
6.9 KiB
Plaintext
194 lines
6.9 KiB
Plaintext
|
|
MSDS - ALUMINUM CHLORIDE, ANHYDROUS
|
|
|
|
------------------------------------------------------------------------------
|
|
1 - PRODUCT IDENTIFICATION
|
|
------------------------------------------------------------------------------
|
|
|
|
PRODUCT NAME: ALUMINUM CHLORIDE, ANHYDROUS
|
|
FORMULA: ALCL3
|
|
FORMULA WT: 133.34
|
|
CAS NO.: 07446-70-0
|
|
COMMON SYNONYMS: ALUMINUM TRICHLORIDE; TRICHLORALUMINUM
|
|
PRODUCT CODES: 0504,4929
|
|
EFFECTIVE: 10/29/85
|
|
REVISION #01
|
|
|
|
PRECAUTIONARY LABELLING
|
|
BAKER SAF-T-DATA(TM) SYSTEM
|
|
|
|
HEALTH - 3 SEVERE (POISON)
|
|
FLAMMABILITY - 0 NONE
|
|
REACTIVITY - 3 SEVERE (WATER REACTIVE)
|
|
CONTACT - 3 SEVERE (CORROSIVE)
|
|
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
|
|
|
LABORATORY PROTECTIVE EQUIPMENT
|
|
|
|
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
|
|
|
PRECAUTIONARY LABEL STATEMENTS
|
|
|
|
DANGER
|
|
CAUSES BURNS
|
|
CONTACT WITH WATER OR MOIST AIR LIBERATES IRRITATING GAS.
|
|
REACTS VIOLENTLY WITH WATER, LIBERATING EXCESSIVE HEAT
|
|
MAY CONTAIN GAS UNDER PRESSURE
|
|
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
|
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
|
ADEQUATE VENTILATION. LOOSEN CLOSURE CAUTIOUSLY BECAUSE OF GAS PRESSURE.
|
|
WASH THOROUGHLY AFTER HANDLING.
|
|
|
|
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
|
|
|
------------------------------------------------------------------------------
|
|
2 - HAZARDOUS COMPONENTS
|
|
------------------------------------------------------------------------------
|
|
|
|
COMPONENT % CAS NO.
|
|
|
|
ALUMINUM CHLORIDE 90-100 7446-70-0
|
|
|
|
------------------------------------------------------------------------------
|
|
3 - PHYSICAL DATA
|
|
------------------------------------------------------------------------------
|
|
|
|
BOILING POINT: 182 C ( 360 F) VAPOR PRESSURE(MM HG): N/A
|
|
|
|
MELTING POINT: 194 C ( 381 F) VAPOR DENSITY(AIR=1): 4.5
|
|
|
|
SPECIFIC GRAVITY: 2.44 EVAPORATION RATE: N/A
|
|
(H2O=1) (BUTYL ACETATE=1)
|
|
|
|
SOLUBILITY(H2O): DECOMPOSES % VOLATILES BY VOLUME: N/A
|
|
|
|
APPEARANCE & ODOR: ORANGE TO YELLOW THROUGH GRAY TO WHITE POWDER.
|
|
|
|
------------------------------------------------------------------------------
|
|
4 - FIRE AND EXPLOSION HAZARD DATA
|
|
------------------------------------------------------------------------------
|
|
|
|
FLASH POINT (CLOSED CUP: N/A NFPA 704M RATING: 3-0-2
|
|
|
|
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
|
|
|
FIRE EXTINGUISHING MEDIA
|
|
USE DRY CHEMICAL OR CARBON DIOXIDE. DO NOT USE WATER.
|
|
|
|
SPECIAL FIRE-FIGHTING PROCEDURES
|
|
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
|
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
|
DO NOT GET WATER INSIDE CONTAINERS.
|
|
|
|
UNUSUAL FIRE & EXPLOSION HAZARDS
|
|
A VIOLENT EXOTHERMIC REACTION OCCURS WITH WATER. SUFFICIENT HEAT
|
|
MAY BE PRODUCED TO IGNITE COMBUSTIBLE MATERIALS.
|
|
|
|
TOXIC GASES PRODUCED
|
|
HYDROGEN CHLORIDE
|
|
|
|
------------------------------------------------------------------------------
|
|
5 - HEALTH HAZARD DATA
|
|
------------------------------------------------------------------------------
|
|
|
|
THRESHOLD LIMIT VALUE (TLV/TWA): 2 MG/M3 ( PPM)
|
|
|
|
TOXICITY: LD50 (ORAL-MOUSE)(MG/KG) - 770
|
|
|
|
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
|
|
|
EFFECTS OF OVEREXPOSURE
|
|
INGESTION MAY CAUSE IRRITATION AND BURNING TO MOUTH AND STOMACH.
|
|
CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS.
|
|
|
|
TARGET ORGANS
|
|
NONE IDENTIFIED
|
|
|
|
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
|
NONE IDENTIFIED
|
|
|
|
|
|
ROUTES OF ENTRY
|
|
NONE INDICATED
|
|
|
|
EMERGENCY AND FIRST AID PROCEDURES
|
|
CALL A PHYSICIAN.
|
|
IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE LARGE AMOUNTS OF
|
|
WATER.
|
|
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
|
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
|
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
|
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
|
|
WASH CLOTHING BEFORE RE-USE.
|
|
|
|
------------------------------------------------------------------------------
|
|
6 - REACTIVITY DATA
|
|
------------------------------------------------------------------------------
|
|
|
|
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
|
|
|
CONDITIONS TO AVOID: MOISTURE
|
|
|
|
INCOMPATIBLES: WATER
|
|
|
|
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE
|
|
|
|
------------------------------------------------------------------------------
|
|
7 - SPILL AND DISPOSAL PROCEDURES
|
|
------------------------------------------------------------------------------
|
|
|
|
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
|
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. DO
|
|
NOT USE WATER.
|
|
WITH CLEAN SHOVEL, PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER.
|
|
MOVE CONTAINER(S) FROM SPILL AREA.
|
|
|
|
DISPOSAL PROCEDURE
|
|
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
|
ENVIRONMENTAL REGULATIONS.
|
|
|
|
EPA HAZARDOUS WASTE NUMBER: D002, D003 (CORROSIVE, REACTIVE WASTE)
|
|
|
|
------------------------------------------------------------------------------
|
|
8 - PROTECTIVE EQUIPMENT
|
|
------------------------------------------------------------------------------
|
|
|
|
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
|
TLV REQUIREMENTS.
|
|
|
|
RESPIRATORY PROTECTION: NONE REQUIRED WHERE APPROPRIATE VENTILATION
|
|
CONDITIONS EXIST. IF THE TLV IS EXCEEDED, A SELF-
|
|
CONTAINED BREATHING APPARATUS IS ADVISED.
|
|
|
|
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
|
RECOMMENDED.
|
|
|
|
------------------------------------------------------------------------------
|
|
9 - STORAGE AND HANDLING PRECAUTIONS
|
|
------------------------------------------------------------------------------
|
|
|
|
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
|
|
|
SPECIAL PRECAUTIONS
|
|
KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
|
|
AND COMBUSTIBLE MATERIALS.
|
|
|
|
------------------------------------------------------------------------------
|
|
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
|
------------------------------------------------------------------------------
|
|
|
|
DOMESTIC (D.O.T.)
|
|
|
|
PROPER SHIPPING NAME ALUMINUM CHLORIDE, ANHYDROUS
|
|
HAZARD CLASS CORROSIVE MATERIAL (SOLID)
|
|
UN/NA UN1796
|
|
LABELS CORROSIVE
|
|
|
|
INTERNATIONAL (I.M.O.)
|
|
|
|
PROPER SHIPPING NAME ALUMINUM CHLORIDE, ANHYDROUS
|
|
HAZARD CLASS 8
|
|
UN/NA UN1726
|
|
LABELS CORROSIVE
|
|
|