194 lines
6.9 KiB
Plaintext
194 lines
6.9 KiB
Plaintext
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MSDS - ALUMINUM CHLORIDE, ANHYDROUS
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------------------------------------------------------------------------------
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1 - PRODUCT IDENTIFICATION
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------------------------------------------------------------------------------
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PRODUCT NAME: ALUMINUM CHLORIDE, ANHYDROUS
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FORMULA: ALCL3
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FORMULA WT: 133.34
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CAS NO.: 07446-70-0
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COMMON SYNONYMS: ALUMINUM TRICHLORIDE; TRICHLORALUMINUM
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PRODUCT CODES: 0504,4929
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EFFECTIVE: 10/29/85
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REVISION #01
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PRECAUTIONARY LABELLING
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BAKER SAF-T-DATA(TM) SYSTEM
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HEALTH - 3 SEVERE (POISON)
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FLAMMABILITY - 0 NONE
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REACTIVITY - 3 SEVERE (WATER REACTIVE)
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CONTACT - 3 SEVERE (CORROSIVE)
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HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
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LABORATORY PROTECTIVE EQUIPMENT
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GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
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PRECAUTIONARY LABEL STATEMENTS
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DANGER
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CAUSES BURNS
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CONTACT WITH WATER OR MOIST AIR LIBERATES IRRITATING GAS.
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REACTS VIOLENTLY WITH WATER, LIBERATING EXCESSIVE HEAT
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MAY CONTAIN GAS UNDER PRESSURE
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DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
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AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
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ADEQUATE VENTILATION. LOOSEN CLOSURE CAUTIOUSLY BECAUSE OF GAS PRESSURE.
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WASH THOROUGHLY AFTER HANDLING.
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SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
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------------------------------------------------------------------------------
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2 - HAZARDOUS COMPONENTS
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------------------------------------------------------------------------------
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COMPONENT % CAS NO.
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ALUMINUM CHLORIDE 90-100 7446-70-0
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------------------------------------------------------------------------------
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3 - PHYSICAL DATA
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------------------------------------------------------------------------------
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BOILING POINT: 182 C ( 360 F) VAPOR PRESSURE(MM HG): N/A
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MELTING POINT: 194 C ( 381 F) VAPOR DENSITY(AIR=1): 4.5
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SPECIFIC GRAVITY: 2.44 EVAPORATION RATE: N/A
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(H2O=1) (BUTYL ACETATE=1)
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SOLUBILITY(H2O): DECOMPOSES % VOLATILES BY VOLUME: N/A
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APPEARANCE & ODOR: ORANGE TO YELLOW THROUGH GRAY TO WHITE POWDER.
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------------------------------------------------------------------------------
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4 - FIRE AND EXPLOSION HAZARD DATA
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------------------------------------------------------------------------------
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FLASH POINT (CLOSED CUP: N/A NFPA 704M RATING: 3-0-2
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FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
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FIRE EXTINGUISHING MEDIA
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USE DRY CHEMICAL OR CARBON DIOXIDE. DO NOT USE WATER.
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SPECIAL FIRE-FIGHTING PROCEDURES
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FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
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BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
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DO NOT GET WATER INSIDE CONTAINERS.
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UNUSUAL FIRE & EXPLOSION HAZARDS
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A VIOLENT EXOTHERMIC REACTION OCCURS WITH WATER. SUFFICIENT HEAT
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MAY BE PRODUCED TO IGNITE COMBUSTIBLE MATERIALS.
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TOXIC GASES PRODUCED
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HYDROGEN CHLORIDE
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------------------------------------------------------------------------------
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5 - HEALTH HAZARD DATA
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------------------------------------------------------------------------------
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THRESHOLD LIMIT VALUE (TLV/TWA): 2 MG/M3 ( PPM)
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TOXICITY: LD50 (ORAL-MOUSE)(MG/KG) - 770
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CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
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EFFECTS OF OVEREXPOSURE
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INGESTION MAY CAUSE IRRITATION AND BURNING TO MOUTH AND STOMACH.
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CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS.
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TARGET ORGANS
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NONE IDENTIFIED
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MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
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NONE IDENTIFIED
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ROUTES OF ENTRY
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NONE INDICATED
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EMERGENCY AND FIRST AID PROCEDURES
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CALL A PHYSICIAN.
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IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE LARGE AMOUNTS OF
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WATER.
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IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
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RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
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IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
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AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
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WASH CLOTHING BEFORE RE-USE.
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------------------------------------------------------------------------------
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6 - REACTIVITY DATA
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------------------------------------------------------------------------------
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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
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CONDITIONS TO AVOID: MOISTURE
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INCOMPATIBLES: WATER
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DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE
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------------------------------------------------------------------------------
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7 - SPILL AND DISPOSAL PROCEDURES
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------------------------------------------------------------------------------
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STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
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WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. DO
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NOT USE WATER.
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WITH CLEAN SHOVEL, PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER.
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MOVE CONTAINER(S) FROM SPILL AREA.
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DISPOSAL PROCEDURE
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DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
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ENVIRONMENTAL REGULATIONS.
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EPA HAZARDOUS WASTE NUMBER: D002, D003 (CORROSIVE, REACTIVE WASTE)
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------------------------------------------------------------------------------
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8 - PROTECTIVE EQUIPMENT
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------------------------------------------------------------------------------
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VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
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TLV REQUIREMENTS.
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RESPIRATORY PROTECTION: NONE REQUIRED WHERE APPROPRIATE VENTILATION
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CONDITIONS EXIST. IF THE TLV IS EXCEEDED, A SELF-
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CONTAINED BREATHING APPARATUS IS ADVISED.
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EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
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RECOMMENDED.
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------------------------------------------------------------------------------
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9 - STORAGE AND HANDLING PRECAUTIONS
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------------------------------------------------------------------------------
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SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
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SPECIAL PRECAUTIONS
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KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
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AND COMBUSTIBLE MATERIALS.
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------------------------------------------------------------------------------
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10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
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------------------------------------------------------------------------------
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DOMESTIC (D.O.T.)
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PROPER SHIPPING NAME ALUMINUM CHLORIDE, ANHYDROUS
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HAZARD CLASS CORROSIVE MATERIAL (SOLID)
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UN/NA UN1796
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LABELS CORROSIVE
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INTERNATIONAL (I.M.O.)
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PROPER SHIPPING NAME ALUMINUM CHLORIDE, ANHYDROUS
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HAZARD CLASS 8
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UN/NA UN1726
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LABELS CORROSIVE
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