174 lines
7.2 KiB
Plaintext
174 lines
7.2 KiB
Plaintext
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MSDS - AMMONIUM PICRATE
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===========================================================================
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Ingredients/Identity Information
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===========================================================================
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Proprietary: NO
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Ingredient: AMMONIUM PICRATE (SARA III)
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Ingredient Sequence Number: 01
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Percent: >90
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NIOSH (RTECS) Number: BS3855000
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CAS Number: 131-74-8
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OSHA PEL: NOT ESTABLISHED
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ACGIH TLV: NOT ESTABLISHED
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Other Recommended Limit: NONE RECOMMENDED
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-------------------------------------
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Proprietary: NO
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Ingredient: WATER (CONTAMINANT)
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Ingredient Sequence Number: 02
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Percent: >10
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NIOSH (RTECS) Number: ZC0110000
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CAS Number: 7732-18-5
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OSHA PEL: NOT ESTABLISHED
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ACGIH TLV: NOT ESTABLISHED
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Other Recommended Limit: NONE RECOMMENDED
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===========================================================================
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Physical/Chemical Characteristics
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===========================================================================
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Appearance And Odor: CRYSTALS;YELLOW;ODOR NOT REPORTED
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Boiling Point: 793F,423C
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Melting Point: DECOMPOSES
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Specific Gravity: 1.7
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Solubility In Water: SLIGHT
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Magnetism (Milligauss): N/P
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Report for NIIN: 00D002973
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===========================================================================
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Fire and Explosion Hazard Data
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Flash Point Method: N/P
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Extinguishing Media: DRY CHEMICAL,SAND,WATER SPRAY OR FOAM.
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Special Fire Fighting Proc: SUBSTANCE DOES NOT BURN READILY ITSELF.USE
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FLOODING QUANTITIES OF WATER AS A FOG AND TO COOL FIRE EXPOSED CONTAINERS.
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SPRAY WATER FROM AS FAR AWAY AS POSSIBLE.
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Unusual Fire And Expl Hazrds: DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT
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OR FLAME.
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===========================================================================
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Reactivity Data
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Stability: NO
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Cond To Avoid (Stability): EXPLOSION HAZARD WHEN EXPOSED TO SHOCK,HEAT,
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FLAMES(ESP.WHEN CONTAMINATED WITH METALS).
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Materials To Avoid: METAL PICRATES(EXPLODES),METALS(EXPLODES AT 572F),
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REDUCING MATERIALS(VIGOROUS REACTION).
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Hazardous Decomp Products: AMMONIA FUMES(CORROSIVE),OXIDES OF NITROGEN AND
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CARBON(TOXIC).
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Hazardous Poly Occur: NO
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Conditions To Avoid (Poly): NONE
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===========================================================================
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Health Hazard Data
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LD50-LC50 Mixture: NOT REPORTED
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Route Of Entry - Inhalation: YES
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Route Of Entry - Skin: YES
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Route Of Entry - Ingestion: YES
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Health Haz Acute And Chronic: INHAL:IRRITANT.SKIN:IRRITANT/SENSITIZER.ITEM
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IS DERMALLY ABSORBED,POSSIBLY TO TOXIC LEVELS.EYES:ITTITATION.INGEST:TOXIC.
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Carcinogenicity - NTP: NO
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Carcinogenicity - IARC: NO
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Carcinogenicity - OSHA: NO
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Explanation Carcinogenicity: AMMONIUM PICRATE HAS NO CARCINOGENICITY
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STATUS.
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Signs/Symptoms Of Overexp: INHAL:MUCUOUS MEMBRANE IRRITATION,RHINITIS.
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SKIN:SENSITIZATION DERMATITIS.ABSORPTION(THROUGH INHAL OR INGEST)CAUSES
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NAUSEA,VOMITING,DIARRHEA,ABDOM.PAIN,YELLOWING OF SKIN,SKIN ERUPTIONS,
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STUPOR,CONVULSIONS,DEATH.EYES:CONJUNCTIVITIS(FROM ACUTE AND CHRONIC
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EXPOSURE).
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Med Cond Aggravated By Exp: NOT REPORTED.
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Emergency/First Aid Proc: INHAL:REMOVE FROM EXPOSURE.SUPPORT
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BREATHING.CALL PHYSICIAN;TREAT SYMPTOMATICALLY.SKIN:REMOVE CONTAMINATED
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CLOTHING AND SHOES;WASH WITH SOAP(OR MILD DETERGENT) FOR 15-20 MINUTES.CALL
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PHYSICIAN.EYE:WASH WITH WATER OR NORMAL SALINE FOR 15-20 MINUTES.CALL
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PHYSICIAN.INGEST:INDUCE VOMITING(IF CONSCIOUS);KEEP HEAD BELOW HIPS.GET
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PROPMT MEDICAL HELP.
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Report for NIIN: 00D002973
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===========================================================================
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Precautions for Safe Handling and Use
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Steps If Matl Released/Spill: SHUT OF IGNITION SOURCES.DO NOT TOUCH SPILL.
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SMALL SPILL:FLUSH AREA WITH WATER.LARGE SPILL:WET DOWN WITH WATER AND DIKE
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FOR LATER DISPOSAL.REPORTABLE QUANTITY=10 POUNDS.
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Neutralizing Agent: NOT KNOWN.
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Waste Disposal Method: NOT SPECIFIED BY MANUFACTURER.FOLLOW FEDERAL,STATE
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AND LOCAL REGULATIONS.
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Precautions-Handling/Storing: THIS MATERIAL EXPLODES EASILY WHEN DRY FROM
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HEAT OR SHOCK.
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Other Precautions: NONE.
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===========================================================================
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Control Measures
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Respiratory Protection: BY INCREASING LEVELS:1-A DUST AND MIST
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RESPIRATOR+FULL FACEPIECE.2-AIR-PURIFYING FULL FACEPIECE RESPIRATOR+HEPA
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FILTER.3-POWERED AIR-PURIFYING RESP.+HEPA FILTER.4-TYPE C,AIR SUPPLIED
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RESP.4-SCBA IN POSITIVE PRESSURE MODE.
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Ventilation: PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION.
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MECHANICALS SHOULD BE EXPLOSION-PROOF.
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Protective Gloves: CHEMICALLY RESISTANT.
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Eye Protection: SPLASH AND DUST RESISTANT GOGGLES.
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Other Protective Equipment: USE IMPERVIOUS CLOTHING TO PREVENT SKIN
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CONTACT.AN EYE WASH STATION AND QUICK DRENCH SHOWER SHOULD BE AVAILABLE.
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Work Hygienic Practices: USE PRUDENT HYGENIC AND SANITARY PRACTICES.WASH
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HANDS.KEEP FOOD AOUT OF THE WORK AREA.
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Suppl. Safety & Health Data: NONE.
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===========================================================================
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Transportation Data
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===========================================================================
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Trans Data Review Date: 93061
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DOT PSN Code: AST
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DOT Proper Shipping Name: AMMONIUM PICRATE
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DOT Class: 1.1D
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DOT ID Number: UN0004
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DOT Pack Group: II
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DOT Label: EXPLOSIVE 1.1D
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IMO PSN Code: BAL
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IMO Proper Shipping Name: AMMONIUM PICRATE
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IMO Regulations Page Number: 1104
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IMO UN Number: 0004
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IMO UN Class: 1.1 D
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IMO Subsidiary Risk Label: -
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IATA PSN Code: BQR
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IATA UN ID Number: 0004
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IATA UN Class: 1.1D
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Report for NIIN: 00D002973
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AFI Prop. Shipping Name: UNDER REVIEW
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Additional Trans Data: REPORTABLE QUANTITY=10 LBS.MFR SUGGESTS DOT-
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EXPLOSIVE A;UN 0004.
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===========================================================================
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Disposal Data
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===========================================================================
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===========================================================================
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Label Data
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===========================================================================
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Label Required: YES
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Technical Review Date: 02MAR93
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MFR Label Number: UNKNOWN
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Label Status: F
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Common Name: AMMONIUM PICRATE
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Chronic Hazard: YES
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Signal Word: DANGER!
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Acute Health Hazard-Severe: X
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Report for NIIN: 00D002973
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Contact Hazard-Severe: X
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Fire Hazard-Severe: X
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Reactivity Hazard-Severe: X
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Special Hazard Precautions: INHAL:IRRITANT.SKIN:IRRITANT/SENSITIZER.ITEM
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IS DERMALLY ABSORBED,POSSIBLY TO TOXIC LEVELS.EYES:IRRITATION.INGEST:TOXIC.
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INHAL:REMOVE FROM EXPOSURE.SUPPORT BREATHING.CALL PHYSICIAN;TREAT
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SYMPTOMATICALLY.SKIN:REMOVE CONTAMINATED CLOTHING AND SHOES;WASH WITH
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SOAP(OR MILD DETERGENT) FOR 15-20 MINUTES.CALL PHYSICIAN.EYE:WASH WITH
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WATER OR NORMAL SALINE FOR 15-20 MINUTES.CALL PHYSICIAN.INGEST:INDUCE
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VOMITING(IF CONSCIOUS);KEEP HEAD BELOW HIPS.GET PROPMT MEDICAL HELP.
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Protect Eye: Y
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Protect Skin: Y
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Protect Respiratory: Y
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