351 lines
15 KiB
Plaintext
351 lines
15 KiB
Plaintext
|
|
MSDS - Copper(II) chloride dihydrate
|
|
Cupric chloride dihydrate
|
|
|
|
|
|
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
|
|
|
|
+------------+------------------------------------+---------+-----------+
|
|
| CAS# | Chemical Name | % | EINECS# |
|
|
|------------|------------------------------------|---------|-----------|
|
|
| 10125-13-0|Copper(II) chloride dihydrate, reage|99% |unlisted |
|
|
nt (powder), 99% (Titr.)
|
|
+------------+------------------------------------+---------+-----------+
|
|
Hazard Symbols: XN T
|
|
Risk Phrases: 22 25 36 36/37/38
|
|
|
|
**** SECTION 3 - HAZARDS IDENTIFICATION ****
|
|
|
|
EMERGENCY OVERVIEW
|
|
Appearance: Not available.
|
|
WARNING! MAY CAUSE ALLERGIC SKIN REACTION. HYGROSCOPIC. HARMFUL IF
|
|
SWALLOWED. MAY CAUSE SEVERE EYE IRRITATION AND POSSIBLE INJURY. MAY
|
|
CAUSE LIVER AND KIDNEY DAMAGE. CAUSES SEVERE RESPIRATORY TRACT
|
|
IRRITATION. INHALATION OF FUMES MAY CAUSE METAL-FUME FEVER. EYE
|
|
CONTACT MAY RESULT IN PERMANENT EYE DAMAGE. MAY CAUSE SEVERE SKIN
|
|
IRRITATION. CAUSES SEVERE DIGESTIVE TRACT IRRITATION WITH PAIN,
|
|
NAUSEA, VOMITING AND DIARRHEA. MAY CORRODE THE DIGESTIVE TRACT WITH
|
|
HEMORRHAGING AND POSSIBLE SHOCK.
|
|
Target Organs: Kidneys, liver.
|
|
|
|
Potential Health Effects
|
|
Eye:
|
|
Exposure to particulates or solution may cause conjunctivitis,
|
|
ulceration, and corneal abnormalities. Causes redness and pain.
|
|
Skin:
|
|
May cause skin sensitization, an allergic reaction, which becomes
|
|
evident upon re-exposure to this material. Causes redness and pain.
|
|
Skin contact can cause itching, redness, and an eczema-type rash.
|
|
Ingestion:
|
|
Harmful if swallowed. Causes gastrointestinal irritation with
|
|
nausea, vomiting and diarrhea.
|
|
Inhalation:
|
|
Causes severe irritation of upper respiratory tract with coughing,
|
|
burns, breathing difficulty, and possible coma. Inhalation of fumes
|
|
may cause metal fume fever, which is characterized by flu-like
|
|
symptoms with metallic taste, fever, chills, cough, weakness, chest
|
|
pain, muscle pain and increased white blood cell count.
|
|
Chronic:
|
|
Prolonged or repeated skin contact may cause dermatitis. May cause
|
|
liver and kidney damage.
|
|
Chronic toxicity related to copper is found only in individuals with
|
|
Wilson's disease, who are unable to excrete copper. This causes
|
|
retention of copper in the body resulting in damage to the liver,
|
|
kidneys, brain, blood, bones and endocrine glands).
|
|
|
|
|
|
**** SECTION 4 - FIRST AID MEASURES ****
|
|
|
|
Eyes:
|
|
Immediately flush eyes with plenty of water for at least 15 minutes,
|
|
occasionally lifting the upper and lower lids. Get medical aid
|
|
immediately.
|
|
Skin:
|
|
Get medical aid. Flush skin with plenty of soap and water for at
|
|
least 15 minutes while removing contaminated clothing and shoes.
|
|
Ingestion:
|
|
Induce vomiting. If victim is conscious and alert, give 2-4 cupfuls
|
|
of milk or water. Never give anything by mouth to an unconscious
|
|
person. Get medical aid immediately.
|
|
Inhalation:
|
|
Get medical aid immediately. Remove from exposure to fresh air
|
|
immediately. If not breathing, give artificial respiration. If
|
|
breathing is difficult, give oxygen.
|
|
Notes to Physician:
|
|
Treat symptomatically and supportively.
|
|
Penicallamine may be of value as a chelating agent.
|
|
|
|
|
|
**** SECTION 5 - FIRE FIGHTING MEASURES ****
|
|
|
|
General Information:
|
|
Wear appropriate protective clothing to prevent contact with skin
|
|
and eyes. Wear a self-contained breathing apparatus (SCBA) to
|
|
prevent contact with thermal decomposition products. Substance is
|
|
noncombustible.
|
|
Extinguishing Media:
|
|
Substance is noncombustible; use agent most appropriate to
|
|
extinguish surrounding fire.
|
|
Autoignition Temperature: Not applicable.
|
|
Flash Point: Not applicable.
|
|
NFPA Rating: Not published.
|
|
Explosion Limits, Lower: Not available.
|
|
Upper: Not available.
|
|
|
|
|
|
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
|
|
|
|
General Information: Use proper personal protective equipment as indicated
|
|
in Section 8.
|
|
Spills/Leaks:
|
|
Vacuum or sweep up material and place into a suitable disposal
|
|
container. Avoid generating dusty conditions.
|
|
|
|
|
|
**** SECTION 7 - HANDLING and STORAGE ****
|
|
|
|
Handling:
|
|
Wash thoroughly after handling. Minimize dust generation and
|
|
accumulation. Do not get in eyes, on skin, or on clothing. Do not
|
|
ingest or inhale. Use only in a chemical fume hood.
|
|
Storage:
|
|
Store in a tightly closed container. Store in a cool, dry,
|
|
well-ventilated area away from incompatible substances.
|
|
|
|
|
|
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
|
|
|
|
Engineering Controls:
|
|
Local exhaust ventilation may be necessary to control any air
|
|
contaminants to within their TLVs during the use of this product.
|
|
|
|
Exposure Limits
|
|
+--------------------+-------------------+-------------------+-----------------+
|
|
| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|
|
|
|--------------------|-------------------|-------------------|-----------------|
|
|
| Copper(II) chloride|fume: 0.2 mg/m3 |as Cu: 1 mg/m3 |fume, as Cu: 0.1 |
|
|
| dihydrate, reagent|TWA; dusts and | TWA (dusts and | mg/m3 TWA; dust|
|
|
| (powder), 99% (Tit| mists, as Cu: 1 |mists); 0.1 mg/m3 |s and mists, as C|
|
|
| r.) | mg/m3 TWA |TWA (fume) |u: 1 mg/m3 TWA |
|
|
| | (listed under | (listed under | (listed under|
|
|
| | COPPER | COPPER | COPPER |
|
|
+--------------------+-------------------+-------------------+-----------------+
|
|
|
|
OSHA Vacated PELs:
|
|
Copper(II) chloride dihydrate, reagent (powder), 99% (Titr.):
|
|
No OSHA Vacated PELs are listed for this chemical.
|
|
|
|
Personal Protective Equipment
|
|
|
|
Eyes:
|
|
Wear appropriate protective eyeglasses or chemical
|
|
safety goggles as described by OSHA's eye and face
|
|
protection regulations in 29 CFR 1910.133.
|
|
Skin:
|
|
Wear appropriate protective gloves to prevent skin
|
|
exposure.
|
|
Clothing:
|
|
Wear appropriate protective clothing to minimize
|
|
contact with skin.
|
|
Respirators:
|
|
Follow the OSHA respirator regulations found in 29CFR
|
|
1010.134. Always use a NIOSH-approved respirator when
|
|
necessary.
|
|
|
|
|
|
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
|
|
|
|
Physical State: Solid
|
|
Appearance: Not available.
|
|
Odor: Odorless
|
|
pH: 3.0-3.8 @ 5% aq.sol
|
|
Vapor Pressure: Not available.
|
|
Vapor Density: Not available.
|
|
Evaporation Rate: Not available.
|
|
Viscosity: Not available.
|
|
Boiling Point: Not available.
|
|
Freezing/Melting Point: 100_C
|
|
Decomposition Temperature: 100_C
|
|
Solubility: 1150 g/l (5% aq.sol)
|
|
Specific Gravity/Density: 2.5400
|
|
Molecular Formula: Cl2Cu.2H2O
|
|
Molecular Weight: 170.4788
|
|
|
|
|
|
**** SECTION 10 - STABILITY AND REACTIVITY ****
|
|
|
|
Chemical Stability:
|
|
Stable. Stable under normal temperatures and pressures.
|
|
Conditions to Avoid:
|
|
Incompatible materials, acids, excess heat, temperatures above 65_C,
|
|
exposure to moist air or water.
|
|
Incompatibilities with Other Materials:
|
|
Incompatible with hydrazine, nitromethane, and sodium hypobromite. A
|
|
mixture of either potassium or sodium with cupric chloride produces
|
|
a strong explosion on impact. Copper salts can form explosive
|
|
acetylides in contact with acetylene. Copper salts may enhance the
|
|
decomposition of hydrazine.
|
|
Hazardous Decomposition Products:
|
|
Hydrogen chloride, chloride fumes.
|
|
Hazardous Polymerization: Will not occur.
|
|
|
|
|
|
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
|
|
|
|
RTECS#:
|
|
CAS# 10125-13-0: GL7030000
|
|
LD50/LC50:
|
|
Not available.
|
|
Carcinogenicity:
|
|
Copper(II) chloride dihydrate, reagent (powder), 99% (Titr.) -
|
|
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
|
|
Epidemiology:
|
|
No data available.
|
|
Teratogenicity:
|
|
No data available.
|
|
Reproductive Effects:
|
|
No data available.
|
|
Neurotoxicity:
|
|
No data available.
|
|
Mutagenicity:
|
|
No data available.
|
|
Other Studies:
|
|
No data available.
|
|
|
|
|
|
**** SECTION 12 - ECOLOGICAL INFORMATION ****
|
|
|
|
Ecotoxicity:
|
|
Acute aquatic effects: 96-hour LC50; Fathead minnow: 0.43 mg/L
|
|
96-hour LC50; Bluegill sunfish: 1.25 mg/L 48-hour LC50; Rainbow
|
|
trout: 0.4-0.5 mg/L This chemical is expected to cause little oxygen
|
|
depletion in aquatic systems. It has a high potential to affect
|
|
aquatic organisms and secondary waste treatment microorganisms.
|
|
Environmental Fate:
|
|
This chemical is not likely to bioconcentrate.
|
|
Physical/Chemical:
|
|
Not available.
|
|
Other:
|
|
Not available.
|
|
|
|
|
|
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
|
|
|
|
Dispose of in a manner consistent with federal, state, and local regulations.
|
|
RCRA D-Series Maximum Concentration of Contaminants: Not listed.
|
|
RCRA D-Series Chronic Toxicity Reference Levels: Not listed.
|
|
RCRA F-Series: Not listed.
|
|
RCRA P-Series: Not listed.
|
|
RCRA U-Series: Not listed.
|
|
Not listed as a material banned from land disposal according to RCRA.
|
|
|
|
|
|
**** SECTION 14 - TRANSPORT INFORMATION ****
|
|
|
|
US DOT
|
|
Shipping Name: COPPER CHLORIDE
|
|
Hazard Class: 8
|
|
UN Number: UN2802
|
|
Packing Group: III
|
|
IMO
|
|
Shipping Name: COPPER CHLORIDE
|
|
Hazard Class: 8
|
|
UN Number: 2802
|
|
Packing Group: 3
|
|
IATA
|
|
Shipping Name: COPPER CHLORIDE
|
|
Hazard Class: 8
|
|
UN Number: 2802
|
|
Packing Group: 3
|
|
RID/ADR
|
|
Shipping Name: COPPER CHLORIDE
|
|
Dangerous Goods Code: 8(11C)
|
|
UN Number: 2802
|
|
Canadian TDG
|
|
No information available.
|
|
|
|
|
|
**** SECTION 15 - REGULATORY INFORMATION ****
|
|
|
|
A. Federal
|
|
TSCA
|
|
CAS# 10125-13-0 is not on the TSCA Inventory. It is a hydrate and
|
|
exempt from TSCA Inventory requirements (40CFR270.3(u)(2)).
|
|
Health & Safety Reporting List
|
|
None of the chemicals are on the Health & Safety Reporting List.
|
|
Chemical Test Rules
|
|
None of the chemicals in this product are under a Chemical Test Rule.
|
|
Section 12b
|
|
None of the chemicals are listed under TSCA Section 12b.
|
|
TSCA Significant New Use Rule
|
|
None of the chemicals in this material have a SNUR under TSCA.
|
|
CERCLA/SARA
|
|
Section 302 (RQ)
|
|
None of the chemicals in this material have an RQ.
|
|
Section 302 (TPQ)
|
|
None of the chemicals in this product have a TPQ.
|
|
SARA Codes
|
|
CAS # 10125-13-0: acute, chronic.
|
|
Section 313
|
|
No chemicals are reportable under Section 313.
|
|
Clean Air Act:
|
|
This material does not contain any hazardous air pollutants.
|
|
This material does not contain any Class 1 Ozone depletors.
|
|
This material does not contain any Class 2 Ozone depletors.
|
|
Clean Water Act:
|
|
None of the chemicals in this product are listed as Hazardous
|
|
Substances under the CWA.
|
|
None of the chemicals in this product are listed as Priority
|
|
Pollutants under the CWA.
|
|
None of the chemicals in this product are listed as Toxic Pollutants
|
|
under the CWA.
|
|
OSHA:
|
|
None of the chemicals in this product are considered highly hazardous
|
|
by OSHA.
|
|
B. State
|
|
Not present on state lists from CA, PA, MN, MA, FL, or NJ.
|
|
California No Significant Risk Level:
|
|
None of the chemicals in this product are listed.
|
|
|
|
C. International
|
|
Canada
|
|
None of the chemicals in this product are listed on the DSL/NDSL list.
|
|
CAS# 10125-13-0 is not listed on Canada's Ingredient Disclosure List.
|
|
European Labeling in Accordance with EC Directives
|
|
Hazard Symbols: XN T
|
|
Risk Phrases:
|
|
R 22 Harmful if swallowed.
|
|
R 25 Toxic if swallowed.
|
|
R 36 Irritating to eyes.
|
|
R 36/37/38 Irritating to eyes, respiratory system
|
|
and skin.
|
|
Safety Phrases:
|
|
S 22 Do not inhale dust.
|
|
S 24/25 Avoid contact with skin and eyes.
|
|
S 26 In case of contact with eyes, rinse immediately
|
|
with plenty of water and seek medical advice.
|
|
S 37/39 Wear suitable gloves and eye/face
|
|
protection.
|
|
S 44 If you feel unwell, seek medical advice (show
|
|
the label where possible).
|
|
Exposure Limits:
|
|
OEL-ARAB Republic of Egypt:TWA 0.1 mg/m3 (fume). OEL-AUSTRALIA:TWA 0.2
|
|
mg/m3 (fume). OEL-AUSTRALIA:TWA 1 mg/m3 (dust). OEL-BELGIUM:TWA 0.2 m
|
|
g/m3 (fume). OEL-BELGIUM:TWA 1 mg/m3 (dust). OEL-DENMARK:TWA 0.1 mg/m3
|
|
(fume). OEL-DENMARK:TWA 1 mg/m3 (dust). OEL-FINLAND:TWA 0.2 mg/m3 (fu
|
|
me). OEL-FINLAND:TWA 1 mg/m3. OEL-FINLAND:TWA 1 mg/m3 (dust)
|
|
CE:TWA 0.2 mg/m3 (fume). OEL-FRANCE:TWA 1 mg/m3;STEL 2 mg/m3 (dust). O
|
|
EL-GERMANY:TWA 0.1 mg/m3 (fume). OEL-GERMANY:TWA 1 mg/m3. OEL-GERMANY:
|
|
TWA 1 mg/m3 (dust). OEL-HUNGARY:TWA 0.2 mg/m3;STEL 0.4 mg/m3 (dust). O
|
|
EL-INDIA:TWA 0.2 mg/m3 (fume). OEL-THE NETHERLANDS:TWA 02 mg/m3 (fume)
|
|
. OEL-THE NETHERLANDS:TWA 1 mg/m3 (dust). OEL-THE PHILIPPINES:TWA 1.0
|
|
mg/m3 (fume). OEL-POLAND:TWA 0.1 mg/m3 (fume). OEL-RUSSIA:STEL 0.5 ppm
|
|
(1 mg/m3) (dust). OEL-SWEDEN:TWA 0.2 mg/m3 (resp. dust). OEL-SWEDEN:T
|
|
WA 0.2 mg/m3 (fume). OEL-SWEDEN:TWA 1 mg/m3 (total dust). OEL-SWITZERL
|
|
AND:TWA 0.1 mg/m3;STEL 0.2 mg/m3 (fume). OEL-SWITZERLAND:TWA 1 mg/m3;S
|
|
TEL 1 mg/m3. OEL-THAILAND:TWA 0.1 mg/m3 (fume). OEL-THAILAND:TWA 1 mg/
|
|
m3. OEL-UNITED KINGDOM:TWA 0.2 mg/m3 (fume). OEL-UNITED KINGDOM:TWA 1
|
|
mg/m3. OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OEL I
|
|
N NEW ZEALM-7M-7
|
|
|
|
|