196 lines
7.2 KiB
Plaintext
196 lines
7.2 KiB
Plaintext
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MSDS - POTASSIUM CHLORATE
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------------------------------------------------------------------------------
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1 - PRODUCT IDENTIFICATION
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------------------------------------------------------------------------------
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PRODUCT NAME: POTASSIUM CHLORATE
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FORMULA: KCLO3
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FORMULA WT: 122.55
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CAS NO.: 03811-04-9
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NIOSH/RTECS NO.: F00350000
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COMMON SYNONYMS: CHLORIC ACID, POTASSIUM SALT; BERTHOLLET SALT; CHLORATE OF
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POTASH
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PRODUCT CODES: 3024,3031,3028
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EFFECTIVE: 11/11/86
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REVISION #02
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PRECAUTIONARY LABELLING
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BAKER SAF-T-DATA(TM) SYSTEM
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HEALTH - 1 SLIGHT
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FLAMMABILITY - 0 NONE
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REACTIVITY - 3 SEVERE (OXIDIZER)
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CONTACT - 2 MODERATE
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HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
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LABORATORY PROTECTIVE EQUIPMENT
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SAFETY GLASSES; LAB COAT; VENT HOOD; PROPER GLOVES
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PRECAUTIONARY LABEL STATEMENTS
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DANGER
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CAUSES IRRITATION
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STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE OR PRODUCE
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SHOCK-SENSITIVE MIXTURES.
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CLOTHING CONTAMINATED WITH CHLORATE OR ITS SOLUTIONS IS DANGEROUSLY
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FLAMMABLE REMOVE CLOTHING AND KEEP WET UNTIL WASHED THOROUGHLY WITH
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WATER. KEEP AWAY FROM FIRE. SPILLAGE MAY CAUSE FIRE. DO NOT GET ON
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FLOOR. KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS.
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DO NOT STORE NEAR COMBUSTIBLE MATERIALS. AVOID CONTACT WITH EYES, SKIN,
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CLOTHING.
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KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING. IN CASE
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OF FIRE, SOAK WITH WATER. IN CASE OF SPILL, SWEEP UP AND REMOVE. FLUSH SPILL
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AREA WITH WATER.
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SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
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------------------------------------------------------------------------------
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2 - HAZARDOUS COMPONENTS
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------------------------------------------------------------------------------
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COMPONENT % CAS NO.
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POTASSIUM CHLORATE 90-100 3811-04-9
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------------------------------------------------------------------------------
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3 - PHYSICAL DATA
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------------------------------------------------------------------------------
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BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
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MELTING POINT: 356 C ( 673 F) VAPOR DENSITY(AIR=1): 4.20
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SPECIFIC GRAVITY: 2.32 EVAPORATION RATE: N/A
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(H2O=1) (BUTYL ACETATE=1)
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SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: 0
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APPEARANCE & ODOR: COLORLESS, WHITE CRYSTALS WITH NO ODOR.
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------------------------------------------------------------------------------
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4 - FIRE AND EXPLOSION HAZARD DATA
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------------------------------------------------------------------------------
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FLASH POINT (CLOSED CUP N/A) NFPA 704M RATING: 0-0-0 OXY
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FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
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FIRE EXTINGUISHING MEDIA
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USE WATER SPRAY.
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SPECIAL FIRE-FIGHTING PROCEDURES
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FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
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(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
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MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
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USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
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UNUSUAL FIRE & EXPLOSION HAZARDS
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STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
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WHEN EXPOSED TO HEAT, CLOSED CONTAINERS MAY EXPLODE; MAY ALSO GIVE
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OFF HIGHLY TOXIC OR IRRITATING FUMES.
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TOXIC GASES PRODUCED
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HYDROGEN CHLORIDE
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------------------------------------------------------------------------------
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5 - HEALTH HAZARD DATA
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------------------------------------------------------------------------------
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CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
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EFFECTS OF OVEREXPOSURE
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DUST MAY IRRITATE NOSE AND THROAT.
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INGESTION MAY CAUSE NAUSEA, VOMITING AND LOSS OF CONSCIOUSNESS.
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TARGET ORGANS
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NASAL CAVATIES
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MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
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NONE IDENTIFIED
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ROUTES OF ENTRY
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INGESTION, INHALATION, EYE CONTACT, SKIN CONTACT
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EMERGENCY AND FIRST AID PROCEDURES
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CALL A PHYSICIAN.
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IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
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RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
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IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
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LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
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------------------------------------------------------------------------------
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6 - REACTIVITY DATA
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------------------------------------------------------------------------------
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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
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CONDITIONS TO AVOID: HEAT, SHOCK, FRICTION
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INCOMPATIBLES: ORGANIC MATERIALS, COMBUSTIBLE MATERIALS,
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STRONG REDUCING AGENTS
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DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE
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------------------------------------------------------------------------------
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7 - SPILL AND DISPOSAL PROCEDURES
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------------------------------------------------------------------------------
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STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
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WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
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KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL.
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WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
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COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
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DISPOSAL PROCEDURE
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DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
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ENVIRONMENTAL REGULATIONS.
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EPA HAZARDOUS WASTE NUMBER: D003 (REACTIVE WASTE)
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------------------------------------------------------------------------------
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8 - PROTECTIVE EQUIPMENT
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------------------------------------------------------------------------------
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VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
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TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
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RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
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CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
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HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
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EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, UNIFORM, BUTYL
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RUBBER GLOVES ARE RECOMMENDED.
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------------------------------------------------------------------------------
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9 - STORAGE AND HANDLING PRECAUTIONS
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------------------------------------------------------------------------------
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SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
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SPECIAL PRECAUTIONS
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KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
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AND COMBUSTIBLE MATERIALS.
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DO NOT DROP OR SLIDE DRUM QUANTITIES OF PRODUCT ACROSS SHARP PROJECTIONS.
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------------------------------------------------------------------------------
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10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
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------------------------------------------------------------------------------
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DOMESTIC (D.O.T.)
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PROPER SHIPPING NAME POTASSIUM CHLORATE
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HAZARD CLASS OXIDIZER
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UN/NA UN1485
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LABELS OXIDIZER
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INTERNATIONAL (I.M.O.)
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PROPER SHIPPING NAME POTASSIUM CHLORATE
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HAZARD CLASS 5.1
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UN/NA UN1485
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LABELS OXIDIZING AGENT
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