196 lines
7.1 KiB
Plaintext
196 lines
7.1 KiB
Plaintext
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MSDS - NAPHTHALENE
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------------------------------------------------------------------------------
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1 - PRODUCT IDENTIFICATION
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------------------------------------------------------------------------------
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PRODUCT NAME: NAPHTHALENE
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FORMULA: C10H8
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FORMULA WT: 128.18
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CAS NO.: 00091-20-3
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NIOSH/RTECS NO.: QJ0525000
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COMMON SYNONYMS: NAPHTHALIN, NAPHTHENE, CAMPHOR TAR, MOTH BALLS
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PRODUCT CODES: 2718
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EFFECTIVE: 09/03/86
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REVISION #02
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PRECAUTIONARY LABELLING
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BAKER SAF-T-DATA(TM) SYSTEM
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HEALTH - 1 SLIGHT
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FLAMMABILITY - 2 MODERATE
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REACTIVITY - 0 NONE
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CONTACT - 1 SLIGHT
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HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
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LABORATORY PROTECTIVE EQUIPMENT
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SAFETY GLASSES; LAB COAT
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PRECAUTIONARY LABEL STATEMENTS
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CAUTION
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COMBUSTIBLE
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KEEP AWAY FROM HEAT, SPARKS, FLAME.
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KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING. IN CASE
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OF FIRE, SOAK WITH WATER. IN CASE OF SPILL, SWEEP UP AND REMOVE. FLUSH SPILL
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AREA WITH WATER.
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SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
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------------------------------------------------------------------------------
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2 - HAZARDOUS COMPONENTS
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------------------------------------------------------------------------------
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COMPONENT % CAS NO.
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NAPHTHALENE 90-100 91-20-3
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------------------------------------------------------------------------------
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3 - PHYSICAL DATA
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------------------------------------------------------------------------------
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BOILING POINT: 218 C ( 424 F) VAPOR PRESSURE(MM HG): 0.05
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MELTING POINT: 80 C ( 176 F) VAPOR DENSITY(AIR=1): 4.42
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SPECIFIC GRAVITY: 1.14 EVAPORATION RATE: N/A
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(H2O=1) (BUTYL ACETATE=1)
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SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: N/A
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APPEARANCE & ODOR: WHITE CRYSTALLINE VOLATILE SOLID WITH THE ODOR OF
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MOTH BALLS
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------------------------------------------------------------------------------
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4 - FIRE AND EXPLOSION HAZARD DATA
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------------------------------------------------------------------------------
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FLASH POINT (CLOSED CUP 88 C ( 190 F) NFPA 704M RATING: 2-2-0
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FLAMMABLE LIMITS: UPPER - 5.9 % LOWER - 0.9 %
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FIRE EXTINGUISHING MEDIA
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USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR ORDINARY FOAM.
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SPECIAL FIRE-FIGHTING PROCEDURES
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FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
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(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
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MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
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USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
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UNUSUAL FIRE & EXPLOSION HAZARDS
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CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.
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CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE OR EXPLOSION.
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------------------------------------------------------------------------------
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5 - HEALTH HAZARD DATA
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------------------------------------------------------------------------------
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THRESHOLD LIMIT VALUE (TLV/TWA): 50 MG/M3 ( 10 PPM)
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SHORT-TERM EXPOSURE LIMIT (STEL): 75 MG/M3 ( 15 PPM)
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PERMISSIBLE EXPOSURE LIMIT (PEL): 50 MG/M3 ( 10 PPM)
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TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 1780
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LD50 (SCU-MOUSE)(MG/KG) - 969
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LD50 (IV-MOUSE) (MG/KG) - 100
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CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
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EFFECTS OF OVEREXPOSURE
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CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
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INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
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GASTROINTESTINAL IRRITATION.
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TARGET ORGANS
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EYES, SKIN, BLOOD, LIVER, KIDNEYS, CENTRAL NERVOUS SYSTEM
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MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
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NONE IDENTIFIED
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ROUTES OF ENTRY
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INHALATION, INGESTION, ABSORPTION, EYE CONTACT, SKIN CONTACT
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EMERGENCY AND FIRST AID PROCEDURES
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CALL A PHYSICIAN.
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IF SWALLOWED, DO NOT INDUCE VOMITING.
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IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
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RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
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IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
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LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
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------------------------------------------------------------------------------
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6 - REACTIVITY DATA
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------------------------------------------------------------------------------
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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
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CONDITIONS TO AVOID: HEAT, FLAME, SOURCES OF IGNITION
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INCOMPATIBLES: STRONG OXIDIZING AGENTS
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------------------------------------------------------------------------------
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7 - SPILL AND DISPOSAL PROCEDURES
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------------------------------------------------------------------------------
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STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
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WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
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SMOKING, OR FLAMES IN AREA. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
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INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA
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WITH WATER.
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DISPOSAL PROCEDURE
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DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
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ENVIRONMENTAL REGULATIONS.
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EPA HAZARDOUS WASTE NUMBER: U165 (TOXIC WASTE)
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------------------------------------------------------------------------------
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8 - PROTECTIVE EQUIPMENT
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------------------------------------------------------------------------------
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VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
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TLV REQUIREMENTS.
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RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
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CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
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TO 500 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH
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ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE
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THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS
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IS RECOMMENDED.
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EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, RUBBER GLOVES ARE
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RECOMMENDED.
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------------------------------------------------------------------------------
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9 - STORAGE AND HANDLING PRECAUTIONS
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------------------------------------------------------------------------------
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SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
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SPECIAL PRECAUTIONS
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KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
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AWAY FROM HEAT, SPARKS, OR FLAME.
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------------------------------------------------------------------------------
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10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
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------------------------------------------------------------------------------
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DOMESTIC (D.O.T.)
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PROPER SHIPPING NAME NAPHTHALENE (AIR AND WATER ONLY)
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HAZARD CLASS ORM-A
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UN/NA UN1334
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LABELS NONE
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REPORTABLE QUANTITY 100 LBS.
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INTERNATIONAL (I.M.O.)
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PROPER SHIPPING NAME NAPHTHALENE, CRUDE OR REFINED
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HAZARD CLASS 4.1
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UN/NA UN1334
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LABELS FLAMMABLE SOLID
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