278 lines
15 KiB
Plaintext
278 lines
15 KiB
Plaintext
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#34
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Improvised Explosives
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Gelatine Explosive from Anti-Freeze
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</>-<\>-</>-<\>-</>-<\>-</>-<\>-</>-<\>
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Written by: The Lich
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This explosive is almost the same as the nitro-gelatin plastique
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explosive exept that it is supple and pliable to -10 to -20 deg. C..
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Antifreeze is easier to obtain than glycerine and is usually cheaper. It
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needs to be freed of water before the manufacture and this can be done
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by treating it with calcium chlor- ide until a specific gravity of 1.12
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@ o deg. C. or 1.11 @ 20 deg. C. is obtained. This can be done by adding
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calcium chloride to the antifreeze and checking with a hydrometer and
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continue to add calcium chloride until the proper reading is obtained.
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The antifreeze is then filtered to remove the calcium chloride from the
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liquid. This explosive is superior to nitro-gelatin in that it is easier
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to collidon the IMR smokeless powder into the explosive and that the
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50/50 ether ethyl alcohol can be done away with. It is superior in that
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the formation of the collidon is done very rapidly by the nitroethelene
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glycol. It's detonation properties are practically the same as the
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nitro- gelatine. Like the nitro-gelatine it is highly flammable and if
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caught on fire the chances are good that the flame will progress to
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detonation. In this explosive as in nitro-gelatine the addition of 1%
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sodium carbonate is a good idea to reduce the chance of recidual acid
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being present in the final explos- ive. The following is a slightly
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different formula than nitro-gelatine:
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Nitro-glycol 75%
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Guncotton (IMR) 6%
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Potassium Nitrate 14%
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Flour (baking) 5%
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In this process the 50/50 step is omitted. Mix the potassium nitrate
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with the nitro-glycol. Remember that this nitro-glycol is just as
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sensitive to shock as is nitroglycerin. The next step is to mix in the
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flour and sodium carbonate. Mix these by kneading with gloved hands
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until the mixture is uniform. This kneading should be done gently and
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slowly. The mixture should be uniform when the IMR smokeless powder is
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added. Again this is kneaded to uniformity. Use this explosive as soon
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as possible. If it must be stored, store in a cool, dry place (0-10 deg.
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C.). This explosive should detonate at 7600-7800 m/sec.. These two
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explosives are very powerful and should be sensitive to a #6 blasting
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cap or equivelent. These explosives are dangerous and should not be made
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unless the manufacturer has had experience with this type compound. The
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foolish and ignor- ant may as well forget these explosives as they won't
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live to get to use them. Don't get me wrong, these explosives have been
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manufactured for years with an amazing record of safety. Millions of
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tons of nitroglycerine have been made and used to manufacture dynamite
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and explosives of this nature with very few mis- haps. Nitroglycerin and
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nitroglycol will kill and their main victims are the stupid and
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foolhardy. Before manufacturing these explosives take a drop of
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nitroglycerin and soak into a small piece of filter paper and place it
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on an anvil. Hit this drop with a hammer and don't put any more on the
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anvil. See what I mean! This explosive compound is not to be taken
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lightly. If there are any doubts DON'T.
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</>-<\>-</>-<\>-</>-<\>-</>-<\>-</>-<\>
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Improvised Explosives
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Plastique Explosive from Aspirin
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</>-<\>-</>-<\>-</>-<\>-</>-<\>-</>-<\>
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Written by: The Lich
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This explosive is a phenol dirivative. It is toxic and explosive
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compounds made from picric acid are poisonous if inhaled, ingested, or
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handled and absor- bed through the skin. The toxicity of this explosive
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restrict's its use due to the fact that over exposure in most cases
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causes liver and kidney failure and sometimes death if immediate
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treatment is not obtained.
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This explosive is a cousin to T.N.T. but is more powerful than it's
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cousin. It is the first explosive used militarily and was adopted in
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1888 as an artillery shell filler. Originally this explosive was derived
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from coal tar but thanx to modern chemistry you can make this explosive
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easily in approximately three hours from acetylsalicylic acid (aspirin
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purified).
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This procedure involves dissolving the acetylsalicylic acid in warm
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sulfuric acid and adding sodium or potassium nitrate which nitrates the
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purified aspirin and the whole mixture drowned in water and filtered to
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obtain the final pro- duct. This explosive is called trinitrophenol.
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Care should be taken to ensure that this explosive is stored in glass
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containers. Picric acid will form dang- erous salts when allowed to
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contact all metals exept tin and aluminum. These salts are primary
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explosive and are super sensitive. They also will cause the detonation
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of the picric acid.
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To make picric acid obtain some aspirin. The cheaper brands work best
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but buffered brands should be avoided. Powder these tablets to a fine
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consistancy. To extract the acetylsalicylic acid from this powder place
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this powder in methyl alcohol and stir vigorously. Not all of the powder
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will dissolve. Filter this powder out of the alcohol. Again wash this
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powder that was filtered out of the alcohol with more alcohol but with a
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lesser amount than the first extrac- tion. Again filter the remaining
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powder out of the alcohol. Combine the now clear alcohol and allow it to
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evaporate in a pyrex dish. When the alcohol has evaporated there will be
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a surprising amount of crystals in the bottom of the pyrex dish.
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Take fourty grams of these purified acetylsalicylic acid crystals and
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dissolve them in 150 ml. of sulfuric acid (98%, specify gravity 1.8) and
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heat to diss- olve all the crystals. This heating can be done in a
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common electric frying pan with the thermostat set on 150 deg. F. and
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filled with a good cooking oil. When all the crystals have dissolved in
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the sulfuric acid take the beaker, that you've done all this dissolving
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in (600 ml.), out of the oil bath. This next step will need to be done
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with a very good ventilation system (it is a good idea to do any
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chemistry work such as the whole procedure and any procedure on this
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disk with good ventilation or outside). Slowly start adding 58 g. of
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sodium nitrate or 77 g. of potassium nitrate to te acid mixture in the
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beaker very slowly in small portions with vigorous stirring. A red gas
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(nitrogen tri- oxide) will be formed and this should be avoided. The
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mixture is likely to foam up and the addition should be stopped until
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the foaming goes down to prevent the overflow of the acid mixture in the
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beaker. When the sodium or potassium nitrate has been added the mixture
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is allowed to cool somewhat (30- 40 deg. C.). The solution should then
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be dumped slowly into twice it's volume of crushed ice and water. The
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brilliant yellow crystals will form in the water. These should be
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filtered out and placed in 200 ml. of boiling distilled water. This
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water is allowed to cool and then the crystals are then filtered out of
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the water. These crystals are a very, very pure trinitrophenol. These
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crystals are then placed in a pyrex dish and places in an oil bath and
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heated to 80 deg. C. and held there for 2 hours. This temperature is
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best maintained and checked with a thermometer. The crystals are then
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powdered in small quantities to a face powder consistency. These
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powdered crystals are then mixed with 10% by weight wax and 5% vaseline
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which are heated to melting temperature and poured into the crystals.
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The mixing is best done by kneading together with gloved hands. This
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explosive should have a useful plsticity range of 0-40 deg. C.. The
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detonation velocity should be around 7000 m/sec.. It is toxic to handle
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but simply made from common ingredients and is suitable for most
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demolition work requiring a moderately high detonation velocity. It is
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very suitable for shaped charges and some steel cutting charges. It is
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not as good an explosive as C-4 or other R.D.X. based explosives but it
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is much easier to make. Again this explosive is very toxic and should be
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treated with great care. AVOID HANDLING BARE-HANDED, BREATHING DUST AND
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FUMES, AVOID ANY CHANCE OF INGESTION. AFTER UTENSILS ARE USED FOR THE
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MANUFACTURE OF THIS EXPLOSIVE RETIRE THEM FROM THE KITCHEN AS THE CHANCE
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OF POISONING IS NOT WORTH THE RISK. THIS EXPLOSIVE, IF MANUFACTURED AS
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ABOVE, AHOULD BE SAFE IN STORAGE BUT WITH ANY HOMEMADE EXPLOSIVE STORAGE
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OS NOT RECOMENDED AND EXPLOSIVES SHOULD BE MADE UP AS NEEDED. A V O I D
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C O N T A C T W I T H A L L M E T A L S E X E P T T I N
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</>-<\>-</>-<\>-</>-<\>-</>-<\>-</>-<\>
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Improvised Explosives
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Plastique Explosive from Bleach
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</>-<\>-</>-<\>-</>-<\>-</>-<\>-</>-<\>
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Written by: The Lich
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This explosive is a potassium chlorate explosive. This explosive and
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explo- sives of similar composition were used in World War II as the
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main explosive filler in gernades, land mines, and mortar used by
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French, German, and other forces involoved in that conflict. These
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explosives are relatively safe to manufacture. One should strive to make
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sure these explosives are free of sulfur, sulfides, and picric acid. The
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presence of these compounds result in mixtures that are or can become
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highly sensitive and possibly decompose ex- plosively while in storage.
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The manufacture of this explosive from bleach is given as just an
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expediant method. This method of manufacturing potassium chlorate is not
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economical due to the amount of energy used to boil the sol- ution and
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cause the 'dissociation' reaction to take place. This procedure does
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work and yields a relatively pure and a sulfur/sulfide free product.
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These explosives are very cap sensitive and require only a #3 cap for
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instigating detonation. To manufacture potassium chlorate from bleach
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(5.25% sodium hypochlorite solution) obtain a heat source (hot plate
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stove etc.) a battery hydrometer, a large pyrex or enameled steel
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container (to weigh chemicals), and some potassium chloride (sold as
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salt substitute). Take one gallon of bleach, place it in the container
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and begin heating it. While this solution heats, weigh out 63 g.
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potassium chloride and add this to the bleach being heated. Bring this
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solution to a boil and boiled until when checked by a hydrometer the
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reading is 1.3 (if a battery hydrometer is used it should read full
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charge).
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When the reading is 1.3 take the solution and let it cool in the
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refrigerator until it's between room temperature and 0 deg. C.. Filter
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out the crystals that have formed and save them. Boil the solution again
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until it reads 1.3 on the hydrometer and again cool the solution. Filter
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out the crystals that have formed and save them. Boil this solution
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again and cool as before. Filter and save the crystals. Take these
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crystals that have been saved and mix them with distilled water in the
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following proportions: 56 g. per 100 ml. distilled water. Heat this
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solution until it boils and allow it to cool. Filter the solution and
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save the crystals that form upon cooling. The process if purifi- cation
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is called fractional crystalization. These crystals should be relatively
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pure potassium chlorate.
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Powder these to the consistency of face powder (400 mesh) and heat
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gently to drive off all moisture. Melt five parts vasoline and five
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parts wax. Dissolve this in white gasoline (camp stove gasoline) and
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pour this liquid on 90 parts potassium chlorate (the crystals from the
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above operation) in a plastic bowl. Knead this liquid into the potassium
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chlorate until immediately mixed. Allow all the gasoline to evaporate.
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Place this explosive in a cool, dry place. Avoid friction, sulfur,
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sulfide, and phosphorous compounds. This explosive is best molded to the
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desired shape and density (1.3g./cc.) and dipped in wax to water proof.
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These block type charges guarantee the highest detonation velocity. This
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explosive is really not suited to use in shaped charge applications due
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to its relatively low detonation velocity. It is comparable to 40%
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ammonia dynamite and can be considered the same for the sake of charge
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computation. If the potassium chlorate is bought and not made it is put
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into the manufacture pro- cess in the powdering stages preceding the
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addition of the wax/vaseline mix- ture. This explosive is bristant and
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powerful. The addition of 2-3% aluminum powder increases its blast
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effect. Detonation velocity is 3300 m/sec..
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</>-<\>-</>-<\>-</>-<\>-</>-<\>-</>-<\>
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Improvised Explosives
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Plastique Explosives From
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Swimming Pool Clorinating Compound
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</>-<\>-</>-<\>-</>-<\>-</>-<\>-</>-<\>
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Written by: The Lich
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This explosive is a chlorate explosive from bleach. This method of
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production of potassium or sodium chlorate is easier and yields a more
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pure product than does the plastique explosive from bleach process. In
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this reaction the H.T.H. (calcium hypochlorite CaC10) is mixed with
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water and heated with either sodium chloride (table salt, rock salt) or
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potassium chloride (salt substitute). The latter of these salts is the
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salt of choice due to the easy crystalization of the potassium chlorate.
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This mixture will need to be boiled to ensure complete reaction of the
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ingredients. Obtain some H.T.H. swimming pool chlorination compound or
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equivilant (usually 65% calcium hypochlorite). As with the bleach
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process mentioned earlier the reaction described below is also a
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dissociation reaction. In a large pyrex glass or enamled steel container
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place 1200g. H.T.H. and 220g. potassium chloride or 159g. sodium
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chloride. Add enough boiling water to dissolve the powder and boil this
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solution. A chalky substance (calcium chloride) will be formed. When the
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formation of this chalky substance is no longer formed the solution is
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filtered while boiling hot. If potassium chloride was used potassium
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chlorate will be formed. This potassium chlorate will drop out or
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crystalize as the clear liquid left after filtering cools. These
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crystals are filtered out when the solution reaches room temperature. If
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the sodium chloride salt was used this clear filtrate (clear liquid
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after filter- ation) will need to have all water evaporated. This will
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leave crystals which should be saved.
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These crystals should be heated in a slightly warm oven in a pyrex dish
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to drive off all traces of water (40-75 deg. C.). These crystals are
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ground to a very fine powder (400 mesh).
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If the sodium chloride salt is used in the initial step the
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crystalization is much more time consuming. The potassium chloride is
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the salt to use as the resulting product will crystalize out of the
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solution as it cools. The powdered and completely dry chlorate crystals
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are kneaded together with vaseline in a plastic bowl. ALL CHLORATE BASED
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EXPLOSIVES ARE SENSITIVE TO FRICTION AND SHOCK AND THESE SHOULD BE
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AVOIDED. If sodium chloride is used in this explosive it will have a
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tendancy to cake and has a slightly lower detonation velocity. This
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explosive is composed of the following:
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potassium/sodium chlorate 90%
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vaseline 10%
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The detonation velocity can be raised to a slight extent by the
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addition of 2-3% aluminum sunstituted for 2-3% of the vaseline. This
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addition of this aluminum will give the explosive a bright flash if set
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off at night which will ruin night vision for a short while. The
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detonation velocity of this explosive is approximately 3200 m/sec. for
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the potassium salt and 2900 m/sec. for the sodium salt based explosive.
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