181 lines
6.6 KiB
Plaintext
181 lines
6.6 KiB
Plaintext
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MSDS - POLY(VINYL ALCOHOL)
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------------------------------------------------------------------------------
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1 - PRODUCT IDENTIFICATION
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------------------------------------------------------------------------------
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PRODUCT NAME: POLY(VINYL ALCOHOL)
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FORMULA: [-CH2CHOH-]N
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FORMULA WT: .00
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CAS NO.: 09002-89-5
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NIOSH/RTECS NO.: TR8100000
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COMMON SYNONYMS: ELVANOL; ETHENOL HOMAPOLYMER; PVA; POLYVIOL; VINOL; ALVYL
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PRODUCT CODES: U229,U228,U227,U232
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EFFECTIVE: 03/18/87
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REVISION #02
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PRECAUTIONARY LABELLING
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BAKER SAF-T-DATA(TM) SYSTEM
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HEALTH - 0 NONE
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FLAMMABILITY - 2 MODERATE
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REACTIVITY - 0 NONE
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CONTACT - 0 NONE
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HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
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LABORATORY PROTECTIVE EQUIPMENT
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SAFETY GLASSES; LAB COAT; CLASS B EXTINGUISHER
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PRECAUTIONARY LABEL STATEMENTS
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CAUTION
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COMBUSTIBLE
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CAUSES EYE IRRITATION
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KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
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KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING. IN CASE OF
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FIRE, USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. FLUSH
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SPILL AREA WITH WATER SPRAY.
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SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
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------------------------------------------------------------------------------
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2 - HAZARDOUS COMPONENTS
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------------------------------------------------------------------------------
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COMPONENT % CAS NO.
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POLY(VINYL ALCOHOL) 90-100 9002-89-5
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------------------------------------------------------------------------------
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3 - PHYSICAL DATA
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------------------------------------------------------------------------------
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BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
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MELTING POINT: 200 C ( 392 F) DECOMPOSES VAPOR DENSITY(AIR=1): N/A
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SPECIFIC GRAVITY: 1.26 EVAPORATION RATE: N/A
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(H2O=1) (BUTYL ACETATE=1)
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SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: 0
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APPEARANCE & ODOR: WHITE TO CREAM POWDER WITH NO ODOR.
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------------------------------------------------------------------------------
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4 - FIRE AND EXPLOSION HAZARD DATA
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------------------------------------------------------------------------------
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FLASH POINT (CLOSED CUP 79 C ( 175 F) NFPA 704M RATING: 0-2-0
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FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
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FIRE EXTINGUISHING MEDIA
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USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR ORDINARY FOAM.
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SPECIAL FIRE-FIGHTING PROCEDURES
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FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
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BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
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MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
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TO KEEP FIRE-EXPOSED CONTAINERS COOL.
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UNUSUAL FIRE & EXPLOSION HAZARDS
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DUST MAY FORM EXPLOSIVE MIXTURE WITH AIR.
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CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE OR EXPLOSION.
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TOXIC GASES PRODUCED
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CARBON MONOXIDE, CARBON DIOXIDE
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------------------------------------------------------------------------------
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5 - HEALTH HAZARD DATA
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------------------------------------------------------------------------------
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CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
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EFFECTS OF OVEREXPOSURE
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INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
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CONTACT CAN CAUSE EYE IRRITATION.
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TARGET ORGANS
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NONE IDENTIFIED
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MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
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NONE IDENTIFIED
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ROUTES OF ENTRY
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INHALATION, EYE CONTACT
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EMERGENCY AND FIRST AID PROCEDURES
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CALL A PHYSICIAN.
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IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
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IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
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RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
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IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
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LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
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------------------------------------------------------------------------------
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6 - REACTIVITY DATA
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------------------------------------------------------------------------------
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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
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CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION, DUSTING
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INCOMPATIBLES: STRONG OXIDIZING AGENTS
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DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
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------------------------------------------------------------------------------
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7 - SPILL AND DISPOSAL PROCEDURES
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------------------------------------------------------------------------------
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STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
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WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
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SMOKING, OR FLAMES IN AREA. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
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INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA
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WITH WATER.
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DISPOSAL PROCEDURE
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DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
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ENVIRONMENTAL REGULATIONS.
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------------------------------------------------------------------------------
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8 - PROTECTIVE EQUIPMENT
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------------------------------------------------------------------------------
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VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
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TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
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RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
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CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
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HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
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EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
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RECOMMENDED.
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------------------------------------------------------------------------------
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9 - STORAGE AND HANDLING PRECAUTIONS
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------------------------------------------------------------------------------
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SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
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SPECIAL PRECAUTIONS
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KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
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AWAY FROM HEAT, SPARKS, OR FLAME.
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DO NOT STORE NEAR OXIDIZING MATERIALS.
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------------------------------------------------------------------------------
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10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
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------------------------------------------------------------------------------
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DOMESTIC (D.O.T.)
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PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
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INTERNATIONAL (I.M.O.)
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PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
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