219 lines
8.3 KiB
Plaintext
219 lines
8.3 KiB
Plaintext
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MSDS - ACETONE
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------------------------------------------------------------------------------
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1 - PRODUCT IDENTIFICATION
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------------------------------------------------------------------------------
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PRODUCT NAME: ACETONE
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FORMULA: (CH3)2CO
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FORMULA WT: 58.08
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CAS NO.: 67-64-1
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NIOSH/RTECS NO.: AL3150000
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COMMON SYNONYMS: DIMETHYL KETONE; METHYL KETONE; 2-PROPANONE
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PRODUCT CODES: 9010,9006,9002,9254,9009,9001,9004,5356,A134,9007,9005,9005
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9008
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EFFECTIVE: 08/27/86
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REVISION #02
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PRECAUTIONARY LABELLING
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BAKER SAF-T-DATA(TM) SYSTEM
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HEALTH - 1 SLIGHT
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FLAMMABILITY - 3 SEVERE (FLAMMABLE)
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REACTIVITY - 2 MODERATE
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CONTACT - 1 SLIGHT
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HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
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LABORATORY PROTECTIVE EQUIPMENT
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SAFETY GLASSES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
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PRECAUTIONARY LABEL STATEMENTS
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DANGER
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CAUSES IRRITATION
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EXTREMELY FLAMMABLE
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HARMFUL IF SWALLOWED OR INHALED
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KEEP AWAY FROM HEAT, SPARKS, FLAME. AVOID CONTACT WITH EYES, SKIN, CLOTHING.
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AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
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ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
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USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE.
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FLUSH SPILL AREA WITH WATER SPRAY.
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SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
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------------------------------------------------------------------------------
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2 - HAZARDOUS COMPONENTS
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------------------------------------------------------------------------------
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COMPONENT % CAS NO.
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ACETONE 90-100 67-64-1
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------------------------------------------------------------------------------
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3 - PHYSICAL DATA
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------------------------------------------------------------------------------
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BOILING POINT: 56 C ( 133 F) VAPOR PRESSURE(MM HG): 181
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MELTING POINT: -95 C ( -139 F) VAPOR DENSITY(AIR=1): 2.0
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SPECIFIC GRAVITY: 0.79 EVAPORATION RATE: ~10
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(H2O=1) (BUTYL ACETATE=1)
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SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100
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APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID WITH A FRAGRANT SWEET ODOR.
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------------------------------------------------------------------------------
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4 - FIRE AND EXPLOSION HAZARD DATA
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------------------------------------------------------------------------------
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FLASH POINT (CLOSED CUP: -18 C ( 0 F) NFPA 704M RATING: 1-3-0
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FLAMMABLE LIMITS: UPPER - 13.0 % LOWER - 2.6 %
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FIRE EXTINGUISHING MEDIA
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USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
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(WATER MAY BE INEFFECTIVE.)
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SPECIAL FIRE-FIGHTING PROCEDURES
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FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
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BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
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MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
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TO KEEP FIRE-EXPOSED CONTAINERS COOL.
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UNUSUAL FIRE & EXPLOSION HAZARDS
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VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK.
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CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG
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OXIDIZERS MAY CAUSE FIRE.
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------------------------------------------------------------------------------
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5 - HEALTH HAZARD DATA
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------------------------------------------------------------------------------
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THRESHOLD LIMIT VALUE (TLV/TWA): 1780 MG/M3 ( 750 PPM)
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SHORT-TERM EXPOSURE LIMIT (STEL): 2375 MG/M3 ( 1000 PPM)
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PERMISSIBLE EXPOSURE LIMIT (PEL): 2400 MG/M3 ( 1000 PPM)
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TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 9750
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LD50 (ORAL-MOUSE)(MG/KG) - 3000
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LD50 (IPR-MOUSE)(MG/KG) - 1297
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LD50 (SKN-RABBIT) (G/KG) - 20
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CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
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EFFECTS OF OVEREXPOSURE
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VAPORS MAY BE IRRITATING TO SKIN, EYES, NOSE AND THROAT.
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INHALATION OF VAPORS MAY CAUSE NAUSEA, VOMITING, HEADACHE, OR LOSS OF
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CONSCIOUSNESS.
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LIQUID MAY CAUSE PERMANENT EYE DAMAGE.
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CONTACT WITH SKIN HAS A DEFATTING EFFECT, CAUSING DRYING AND IRRITATION.
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INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
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GASTROINTESTINAL IRRITATION.
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CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
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TARGET ORGANS
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RESPIRATORY SYSTEM, SKIN
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MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
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NONE IDENTIFIED
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ROUTES OF ENTRY
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INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
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EMERGENCY AND FIRST AID PROCEDURES
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CALL A PHYSICIAN.
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IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
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IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
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RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
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IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
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LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
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------------------------------------------------------------------------------
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6 - REACTIVITY DATA
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------------------------------------------------------------------------------
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STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
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CONDITIONS TO AVOID: HEAT, FLAME, SOURCES OF IGNITION
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INCOMPATIBLES: HALOGEN ACIDS AND HALOGEN COMPOUNDS, STRONG BASES,
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STRONG OXIDIZING AGENTS, CAUSTICS, AMINES AND AMMONIA,
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CHLORINE AND CHLORINE COMPOUNDS,
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STRONG ACIDS, ESP. SULFURIC, NITRIC, HYDROCHLORIC
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------------------------------------------------------------------------------
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7 - SPILL AND DISPOSAL PROCEDURES
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------------------------------------------------------------------------------
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STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
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WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
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SMOKING, OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE
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WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE
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ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH
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AREA WITH WATER.
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J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED
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FOR SPILLS OF THIS PRODUCT.
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DISPOSAL PROCEDURE
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DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
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ENVIRONMENTAL REGULATIONS.
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EPA HAZARDOUS WASTE NUMBER: U002 (TOXIC WASTE)
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------------------------------------------------------------------------------
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8 - PROTECTIVE EQUIPMENT
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------------------------------------------------------------------------------
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VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
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TLV REQUIREMENTS.
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RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
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CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
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TO 5000 PPM, A GAS MASK WITH ORGANIC VAPOR
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CANNISTER IS RECOMMENDED. ABOVE THIS LEVEL, A
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SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE
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SHIELD IS ADVISED.
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EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, BUTYL RUBBER
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GLOVES ARE RECOMMENDED.
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------------------------------------------------------------------------------
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9 - STORAGE AND HANDLING PRECAUTIONS
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------------------------------------------------------------------------------
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SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
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SPECIAL PRECAUTIONS
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BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. KEEP CONTAINER
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TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID
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STORAGE AREA.
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------------------------------------------------------------------------------
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10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
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------------------------------------------------------------------------------
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DOMESTIC (D.O.T.)
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PROPER SHIPPING NAME ACETONE
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HAZARD CLASS FLAMMABLE LIQUID
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UN/NA UN1090
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LABELS FLAMMABLE LIQUID
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REPORTABLE QUANTITY 5000 LBS.
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INTERNATIONAL (I.M.O.)
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PROPER SHIPPING NAME ACETONE
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HAZARD CLASS 3.1
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UN/NA UN1090
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LABELS FLAMMABLE LIQUID
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